They may not strum so well, but when it comes to posing with the instrument, these women can certainly make a statement. Here's a rundown on the sexiest guitar girls and we begin with, but of course Shania Twain. With a guitar in hand, the Material Girl looks even hotter. The first lady of France, Carla Bruni may not be hitting the right musical notes, but it's cool to see her laying her hands on the strings.